In situ formation of poly(butyl acrylate)-based non-flammable elastic quasi-solid electrolyte for dendrite-free flexible lithium metal batteries with long cycle life for wearable devices

نویسندگان

چکیده

Abstract With the rapid development of wearable devices, there is an increasing demand for ultra-safe flexible lithium-ion batteries (LIBs) capable delivering high energy density. Because it can provide highest possible capacity 3860 mAh g-1, lithium metal has drawn tremendous research attention. However, Li a highly reactive that grows dendrites during cycling lithium-metal (LMBs). To resolve problem, we developed new non-flammable elastic quasi-solid electrolyte (QSE), which be polymerized in situ and whose composition tailored to achieve elasticity. Moreover, incorporation trimethyl phosphate (TMP) renders non-flammable. Thanks solid interphase (SEI) formed, LMB with QSE displays excellent stability as operated 500 cycles, retention 94%. The corresponding symmetric cell cycled stably more than 500 h. Scanning electron microscopy (SEM) density functional theory (DFT) calculations reveal fluoroethylene carbonate (FEC) critical forming LiF-rich SEI enables long-term stability. In brief, non-flammable, elastic, stable reported first time, very promising application next-generation devices.

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ژورنال

عنوان ژورنال: Energy Storage Materials

سال: 2021

ISSN: ['2405-8297', '2405-8289']

DOI: https://doi.org/10.1016/j.ensm.2020.10.012